FR-4 (Glass Epoxy Laminate) vs PPA (Polyphthalamide): 0% composition overlap. Significantly different materials serving different application areas.
FR-4 (Glass Epoxy Laminate) vs PPA (Polyphthalamide)
Side-by-side chemical composition and mechanical property comparison.
Overview
FR-4 (Glass Epoxy Laminate)
Flame retardant woven fiberglass cloth with epoxy resin binder — the worldwide standard substrate material for printed circuit boards (PCBs). Designated NEMA grade FR-4 and IPC-4101. Good mechanical strength, dimensional stability and electrical insulation up to 130°C (Tg). Dielectric constant 4.2–4.7 at 1 MHz. Self-extinguishing (UL94 V-0). Used for single/multilayer PCBs, electrical insulation boards, structural composites in electronics, test fixtures and jigs. Available in thicknesses 0.1–50 mm.
PPA (Polyphthalamide)
Polyphthalamide — semi-aromatic high-performance polyamide. 55%+ aromatic diacid (TPA/IPA) gives Tg ~125°C and Tm >310°C — far above PA66 (Tg 50°C, Tm 260°C). Much lower moisture absorption than aliphatic PAs. SMT-reflow compatible (260°C+). Trade names: Amodel (Solvay/Syensqo), Zytel HTN (Celanese), Ultramid T (BASF), Grivory HT (EMS). Used for automotive powertrain (thermostat housings, charge air coolers), SMT connectors, LED headlamp housings, and metal-replacement applications to 280°C.
| FR-4 (Glass Epoxy Laminate) | PPA (Polyphthalamide) | |
|---|---|---|
| Material Number | — | — |
| Category | Polymers | Polymers |
| Standard | IPC-4101 | ISO 527-1 |
Mechanical properties
| Property | FR-4 (Glass Epoxy Laminate) | PPA (Polyphthalamide) | Unit |
|---|---|---|---|
| Flexural Strength | 380–480 | — | MPa |
| Tensile Strength | 280–340 | — | MPa |
| Compressive Strength | 350–420 | — | MPa |
Compatibility Assessment
FR-4 (Glass Epoxy Laminate) and PPA (Polyphthalamide) have significantly different compositions (0% overlap). These materials are not interchangeable and serve different application areas.
Automated assessment based on composition analysis
Frequently Asked Questions
Is FR-4 (Glass Epoxy Laminate) the same as PPA (Polyphthalamide)?
FR-4 (Glass Epoxy Laminate) and PPA (Polyphthalamide) have a 0% composition overlap. They are generally not directly interchangeable.
Can I replace FR-4 (Glass Epoxy Laminate) with PPA (Polyphthalamide)?
Generally not recommended. The compositions differ significantly (0% overlap). These materials have different alloying concepts and are intended for different applications.
What is the difference between FR-4 (Glass Epoxy Laminate) and PPA (Polyphthalamide)?
The main differences are in the following elements: overall alloying content. FR-4 (Glass Epoxy Laminate) is a Polymers grade, while PPA (Polyphthalamide) is a Polymers grade.
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Data provided for reference only. Always verify against the applicable specification for critical applications.
All data is for reference only. Equivalents indicate similarity, not identity. Always verify against the applicable specification for safety-critical applications. materialref.com accepts no liability for decisions based on this data.